- (E,Z)-Ajoene: A potent antithrombotic agent from garlic
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A report is presented of the structural characterization and simple synthesis of (E,Z)-ajoene.
- Block,Ahmad,Jain,et al.
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p. 8295 - 8296
(2007/10/02)
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- Gas Phase Reactions, 30. Thioacrolein: The Most Stable Isomer C3H4S and its PE Spectroscopic Proof in the Gas Phase
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The ensemble C3H4S contains 13 valence-"normal" isomers, of which according to MNDO calculations thioacrolein, H2C=C(H)-C(H)=S, should be the energetically most stable.Expectedly, diallyl sulfide decomposes on pyrolysis at 660 K to yield propene and thioacrolein, which can be cool-trapped in a preparative way as mixture of Diels-Alder dimers.Heating of the isomeric dimeres leads in a retrodiene splitting to pure thioacrolein, identified by its PE spectrum which is similar to that of acrolein.
- Bock, Hans,Mohmand, Shamsher,Hirabayashi, Takakuni,Semkow, Andrzej
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p. 1339 - 1348
(2007/10/02)
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