- Metal- And solvent-free synthesis of aniline- And phenol-based triarylmethanes: Via Br?nsted acidic ionic liquid catalyzed Friedel-Crafts reaction
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A beneficial, scalable and efficient methodology for the synthesis of aniline-based triarylmethanes has been established through the double Friedel-Crafts reaction of commercial aldehydes and primary, secondary or tertiary anilines using Br?nsted acidic ionic liquid as a powerful catalyst, namely [bsmim][NTf2]. This protocol was successfully performed under metal- and solvent-free conditions with a broad range of substrates, giving the corresponding aniline-based triarylmethane products in good to excellent yields (up to 99%). In addition, alternative aromatic nucleophiles such as phenols and electron-rich arenes were also studied using this useful approach to achieve a diversity of triarylmethane derivatives in high to excellent yields. This journal is
- Jaratjaroonphong, Jaray,Saeeng, Rungnapha,Senapak, Warapong,Sirion, Uthaiwan,ponpao, nipaphorn
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p. 22692 - 22709
(2021/07/21)
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- SUBSTITUTED OR UNSUBSTITUTED ALLYL GROUP-CONTAINING MALEIMIDE COMPOUND, PRODUCTION METHOD THEREFOR, AND COMPOSITION AND CURED PRODUCT USING SAID COMPOUND
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Bismaleimides (BMI) exhibit excellent heat resistance (high Tg and high resistance to thermal decomposition) compared to epoxy resins and phenolic resins, and therefore, in recent years, more attention is paid to bismaleimides as a resin material for the next-generation devices represented by SiC power semiconductors, in addition to the investigation on the use of bismaleimides for electronic material applications. As such, conventional BMI's are known as highly heat-resistant resins; however, there is a demand for a resin having higher heat resistance for advanced material applications and the like. Thus, an object of the invention is to provide a novel maleimide compound having superior heat resistance. Disclosed is a substituted or unsubstituted allyl group-containing maleimide compound having a structure with three or more benzene rings, having one or more groups each having a substituted or unsubstituted allyl group, and having one or more maleimide groups.
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Paragraph 0261
(2020/11/30)
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- Organic compounds
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Compounds of the general formula (I) a process for their preparation and their use for dyeing and/or printing organic substrates.
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Page/Page column 6
(2010/12/01)
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- Pyrazolone monoazo dyes
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Acid dyes, a process for their preparation and their use for dyeing organic substrates of the general formula (I) wherein the substituents have the meaning as indicated in the claims.
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Page/Page column 6-7
(2010/12/01)
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- Basic monoazo compounds
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The invention relates to basic azo compounds according to formula (I) wherein all substituents are defined as in Claim 1, their production, their use as dyestuffs as well as material dyed with these dyestuffs.
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Page/Page column 7
(2009/07/25)
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- BASIC BISAZO COMPOUNDS
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The invention relates to basic bisazo compounds according to formula (I) wherein all substituents are defined as in Claim 1, their production, their use as dyestuffs as well as material dyed with these dyestuffs.
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Page/Page column 10
(2008/06/13)
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- Microwave-assisted synthesis of 4,4′-diaminotriphenylmethanes
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A fast, efficient and versatile route of synthesis of 4,4′- diaminotriphenylmethanes under microwave irradiation, suitable for parallel library syntheses were developed.
- Guzmán-Lucero,Guzmán,Likhatchev,Martínez-Palou
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p. 1119 - 1122
(2007/10/03)
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