62956-38-1

Basic information

• Product Name: 2-Chloro-3-methylnaphthalene
• Synonyms: 2-Chloro-3-methylnaphthalene
• CAS NO: 62956-38-1
• Molecular Formula: C₁₁H₉Cl
• Molecular Weight: 176.64216
• Mol File: 62956-38-1.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Chloro-3-methylnaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Chloro-3-methylnaphthalene(62956-38-1)
• EPA Substance Registry System: 2-Chloro-3-methylnaphthalene(62956-38-1)

Safety Data

• Hazardous Substances Data: 62956-38-1(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 22, p. 1473, 1957 DOI: 10.1021/jo01362a041

Relevant articles and documents

Cyclization of (2-alkenylphenyl)carbonyl compounds to polycyclic arenes catalyzed by copper(II) trifluoromethanesulfonate or trifluoromethanesulfuric acid

Various polycyclic arenes, such as naphthalenes, tetrahydroantharacenes, tetrahydrotetracenes, dihydropentacenes, and dihydropentaphenes are prepared from 2-alkenylphenyl ketones and aldehydes by the catalytic use of copper(II) trifluoromethanesulfonate (Cu(OTf)2) or trifluoromethanesulfuric acid (TfOH). Copyright

Cyclization of (2-alkenylphenyl)carbonyl compounds to polycyclic arenes catalyzed by copper(II) trifluoromethanesulfonate or trifluoromethanesulfuric acid

Various polycyclic arenes, such as naphthalenes, tetrahydroantharacenes, tetrahydrotetracenes, dihydropentacenes, and dihydropentaphenes are prepared from 2-alkenylphenyl ketones and aldehydes by the catalytic use of copper(II) trifluoromethanesulfonate (Cu(OTf)2) or trifluoromethanesulfuric acid (TfOH). Copyright

Synthesis of Cycloproparenes via Aromatization of 7-Oxanorbornenes with Low-Valent Titanium

1H-Cyclopropanaphthalene 3c and the 2,7-diphenyl-substituted derivative 3a have been synthesized via cycloaddition of the appropriate isobenzofurans 1a and 1b to 1-bromo-2-chlorocyclopropene and aromatization of the adducts with low-valent Ti.The same procedure afforded the 2,7-dimethyl-1H-cyclopropaisoquinoline (15), but failed for the parent azacompound.Reaction of adducts of furans to 1-bromo-2-chlorocyclopropenes with low-valent Ti produced mixtures of cyclopropabenzenes 19 and 1,6-dihalogeno-1,3,5-cycloheptatrienes 18.The latter could be converted to cyclopropabenzenes with BuLi.