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6379-56-2

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Chiral pool based efficient synthesis of the aminocyclitol core and furanoside of (-)- hygromycin A: Formal total synthesis of (-)-hygromycin A
A chiral pool based synthetic strategy that leads from the readily available and inexpensive C2-symmetric tartaric acids to the chiral O-isopropylidenebenzooxazolei- a convenient precursor to the aminocyclitol core of hygromycin A as well as the chiral γ-disilyloxybutyrolactone-a pivotal intermediate to approach to the furanoside of hygromycin A.
Lo, Hong-Jay,Chang, Yuan-Kang,Yan, Tu-Hsin
supporting information
p. 5896 - 5899
(2013/02/23)

Synthesis of (-)-hygromycin a: application of Mitsunobu glycosylation and tethered aminohydroxylation
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Donohoe, Timothy J.,Flores, Aida,Bataille, Carole J. R.,Churruca, Fatima
supporting information; experimental part
p. 6507 - 6510
(2009/12/06)

Total Synthesis of Antibiotic Hygromycin A
The first total synthesis of the antibiotic (-)-hygromycin A (1) has been achieved by a coupling reaction of the sugar moiety (2) and the cyclitol moiety (3).Both components were synthesized in homochiral forms starting from D-glucose.This synthesis fully
Chida, Noritaka,Ohtsuka, Masami,Nakazawa, Keiichi,Ogawa, Seiichiro
p. 2976 - 2983
(2007/10/02)

Total Synthesis of Hygromycin A
The first complete synthesis of antibiotic hygromycin A is reported; coupling of the protected sugar moiety (2) and the aminocyclitol (3) derived from D-glucose as the optically active form, followed by deprotection, gives the product (1) which was identi
Chida, Noritaka,Ohtsuka, Masami,Nakazawa, Keiichi,Ogawa, Seiichiro
p. 436 - 438
(2007/10/02)

More Articles about upstream products of 6379-56-2

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66740-54-3
Hygromycin-hexaacetat

Chemical Properties

Melting Point: 105-109°; mp 110-112° (dec) (Chida)
PKA: 8.9(at 25℃)
PSA: 207.96000
LogP: -1.62710

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