- Remote sp2C-H Carboxylation via Catalytic 1,4-Ni Migration with CO2
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A remote catalytic reductive sp2 C-H carboxylation of arenes with CO2 (1 bar) via 1,4-Ni migration is disclosed. This protocol constitutes the first catalytic 1,4-Ni migration reported to date, thus offering new vistas in the Ni-catalyzed reductive coupling arena while providing an unconventional new platform for incorporating electrophilic sites at remote sp2 C-H linkages.
- B?rjesson, Marino,Duan, Yaya,Janssen-Müller, Daniel,Martin, Ruben,Sahoo, Basudev,Wang, Xueqiang
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supporting information
p. 16234 - 16239
(2020/10/09)
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- Photolysis of Vinyl Halides. Preferential Formation of Vinyl Cations by Copper(II) Salts
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Photolysis of vinyl halides in the presence of copper(II) salts in a significant suppression of product formation derived from vinyl radicals.Photolysis of 1,1-diaryl-2-bromopropenes in the presence of copper(II) salts yielded no 1,1-diaryl-2-propenes.Photolysis of other vinyl halides, i.e., 1,1-diaryl-2-iodopropenes, 1,1-diaryl-2-bromoethylenes, and 1-bromo-2-(p-methoxyphenyl)ethylene, also led to a large decrease in the yields of the reduced olefins derived from the vinyl radicals.Copper(II) triflate was found to be more effective for the oxidation of vinyl radicals than copper(II) acetate.These reactions are explained by the intervention of vinylcopper intermediates and the formation of vinyl cations.
- Kitamura, Tsugio,Kobayashi, Shinjiro,Taniguchi, Hiroshi
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p. 2641 - 2645
(2007/10/02)
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