Arylmaleic anhydrides via Heck arylation of fumaric acid
Palladium-catalyzed arylation of fumaric acid with aryl iodides is found to be a very simple, economic and scalable approach to arylmaleic anhydrides. The reaction is facilitated by the presence of donor moieties on the aryl fragment and does not occur wi
Roshchin, Alexander I.
experimental part
p. 3633 - 3635
(2010/08/13)
CP-263,114 synthetic studies. Construction of an isotwistane ring system via rhodium carbenoid C-H insertion
Described is a rhodium carbenoid C-H insertion strategy for the construction of an isotwistane ring system needed for a late-stage fragmentation en route to the total synthesis of CP-263,114.
Spiegel, David A,Njardarson, Jón T,Wood, John L
p. 6545 - 6554
(2007/10/03)
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