649767-57-7

Basic information

• Product Name: 2-Cyclohexen-1-one, 2,6-dihydroxy-3,6-bis(1-methylethyl)- (9CI)
• Synonyms: 2-Cyclohexen-1-one, 2,6-dihydroxy-3,6-bis(1-methylethyl)- (9CI)
• CAS NO: 649767-57-7
• Molecular Formula: C12H20O3
• Molecular Weight: 212.2854
• Product Categories: ALCOHOL
• Mol File: 649767-57-7.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Cyclohexen-1-one, 2,6-dihydroxy-3,6-bis(1-methylethyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one, 2,6-dihydroxy-3,6-bis(1-methylethyl)- (9CI)(649767-57-7)
• EPA Substance Registry System: 2-Cyclohexen-1-one, 2,6-dihydroxy-3,6-bis(1-methylethyl)- (9CI)(649767-57-7)

Safety Data

• Hazardous Substances Data: 649767-57-7(Hazardous Substances Data)

Upstream product

• 117773-78-1 2-isopropyl-5-methylcyclohexanone 
• 54783-36-7 ξ-diosphenol 
• 110364-40-4 3-iodo-3-methyl-6-isopropyl-1,2-cyclohexanedione 
• 17627-49-5 trans-5-methyl-2-(1-methylethyl)cyclohexanone 

Relevant articles and documents

Photo-irradiation of α-halo carbonyl compounds: A novel synthesis of α-hydroxy- and α,α′-dihydroxyketones

The reaction of α-halo ketones (α-iodocycloalkanones, α-bromocycloalkanones, α-iodo-β-alkoxy esters, and α-iodoacyclicketones) with irradiation under a high-pressure mercury lamp gave the corresponding α-hydroxyketones in good yields. For α-bromoketones, it was found that α-hydroxylation does not occur. However, α-bromoketones were converted into α-hydroxyketones in the presence of KI. In the case of α,α′-diiodo ketones, α,α′-dihydroxyketones, which up to now have scarcely been reported, were obtained. This reaction affords a new, clean and convenient synthetic method for α-hydroxy- and α,α′- dihydroxyketones.

A novel synthesis of α-hydroxy- and α,α′- dihydroxyketone from α-iodo and α,α′-diiodo ketone using photoirradiation

A novel reaction of α-iodo ketone (α-iodocycloalkanone, α-iodo-β-alkoxy ester, and α-iodoacyclicketone) with irradiation under a high-pressure mercury lamp gave the corresponding α-hydroxyketone in good yields. In the case of α,α′- diiodo ketone, α,α′-dihydroxyketone which little has been reported until now was obtained. This reaction affords a new, clean and convenient synthetic method for α-hydroxy- and α,α′- dihydroxyketone.

Oxidative cleavage of the C-C bond of 3,6-dialkylcyclohexane-1,2-diones by cell suspension cultures of Marchantia polymorpha

Biotransformation of 3,6-dialkylcyclohexane-1,2-diones by cell suspension cultures of Marchantia polymorpha involves regio-selective oxidative cleavage of the C-C bond to give the corresponding oxocarboxylic acids shortened by one carbon unit. In the case of cyclohexane-1,2-dione, adipic acid was obtained.

Synthesis of naturally occurring diosphenols and hydroxydiosphenols

Syntheses of diosphenol (3), ψ-diosphenol (4), 6-hydroxydiosphenol (5) and 6-hydroxy-ψ-diosphenol (6), which are constituents of the essential oil from Barosma betulina Bartl. (mountain buchu), are discussed.