65128-45-2Relevant articles and documents
Supramolecular enantiomeric and structural differentiation of amino acid derivatives with achiral pillar[5]arene homologs
Ji, Jiecheng,Li, Yizhou,Xiao, Chao,Cheng, Guo,Luo, Kui,Gong, Qiyong,Zhou, Dayang,Chruma, Jason J.,Wu, Wanhua,Yang, Cheng
supporting information, p. 161 - 164 (2019/12/30)
Complexation of achiral pillar[5]arenes with chiral amines induced strong circular dichroism (CD) signals. The CD responses differed drastically depending on the nature of the amino acid guest, and they significantly varied and part of them even inverted, upon increasing the length of the alkyl chains of the pillar[5]arenes guests. Accordingly, this tactic allowed for the unprecedented simultaneous enantiomeric and structural differentiation of α-amino esters with homologous molecular hosts.
Solvent-free synthesis of pillar[6]arenes
Santra,Kopchuk,Kovalev,Zyryanov,Majee,Charushin,Chupakhin
supporting information, p. 423 - 426 (2016/01/30)
An efficient solvent-free procedure for the synthesis of pillar[6]arenes has been developed. The procedure involves the solid-state condensation of finely milled 1,4-dialkoxybenzene and paraformaldehyde by grinding in the presence of a catalytic amount of H2SO4. The use of organic solvents for the extraction of products has also been avoided. Operational simplicity, compatibility with various 1,4-dialkoxybenzenes, non-chromatographic purification technique, high yields and mild reaction conditions are the notable advantages of this procedure. A large scale reaction demonstrated the practical applicability of this methodology.
Aryl trihydroxyborate salts: Thermally unstable species with unusual gelation abilities
Moy, Cheryl L.,Kaliappan, Raja,McNeil, Anne J.
experimental part, p. 8501 - 8507 (2011/12/04)
A series of aryl trihydroxyborate salts were synthesized and found to form gels in benzene. The compounds were thermally unstable and readily underwent protodeboronation in solution and the solid state. Gelation could be induced without decomposition via sonication. Subsequent characterization studies revealed an unusual dependence of gel properties on alkyl chain length.
Synthesis and characterization of photorefractive polymers containing transition metal complexes as photosensitizer
Peng, Zhonghua,Gharavi, Ali R.,Yu, Luping
, p. 4622 - 4632 (2007/10/03)
This paper reports detailed synthesis and characterization of a hybridized polymer system which combines the ionic transition metal complexes and a conjugated polymer backbone bearing NLO chromophores to manifest a large photorefractive (PR) effect. In th