Reactions of isomeric arylchloropyruvates and glycidates with hydrazines
Reactions of arylchloropyruvic acids esters with aryl- and hetarylhydrazines give rise to pyrazolinedione hydrazones as a result of a tandem condensation of the substituted hydrazines with arylchloropyruvates. In contrast to this process in reaction with hydrazine hydrate a ready reduction unexpectedly occurs by Kizhner-Wolff mechanism affording 3- hydroxydihydrocinnamic acid hydrazide as the principal product. The isomeric arylglycidate reacts along the same pattern. 2005 Pleiades Publishing, Inc.
Enaminone in heterocyclic synthesis: Synthesis of new pyrazolopyrazole, pyrazolothienooxazine and pyrazolothienopyridine derivatives
The chemical reactivity of enaminone 2 toward some nucleophilic and electrophilic reagents was investigated. Enaminone 2 was used as a key precursor for the synthesis of many important heterocyclic compounds. The synthesized compounds were characterized b
Hafiz, Ibrahim Saad Abdel,Reheim, Mohamed Ahmed Mahmoud Abdel,Baker, Safaa Mohamed,Ramiz, Mahmoud Mahfouz
p. 1133 - 1144
(2015/01/30)
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