Comparative photohalogenation of phenylglucopyranoside and its oxidation derivatives
The photobrominations of the peracetylated phenyl thio-1-β-D-glucopyranoside and of the corresponding sulphoxides and sulphone have been investigated. The differences observed in both substrate reactivity and substitution regioselectivity indicate an easier homolysis of the anomeric C-H bond in the thioglycoside.
Praly,Descotes
p. 1133 - 1136
(2007/10/02)
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