657396-97-9

Basic information

• Product Name: Carbamic acid, (4-oxo-2-cyclopenten-1-yl)-, 1,1-dimethylethyl ester (9CI)
• Synonyms: Carbamic acid, (4-oxo-2-cyclopenten-1-yl)-, 1,1-dimethylethyl ester (9CI);tert-butyl N-(4-oxocyclopent-2-en-1-yl)carbamate;tert-Butyl (4-oxocyclopent-2-en-1-yl)carbamate
• CAS NO: 657396-97-9
• Molecular Formula: C10H15NO3
• Molecular Weight: 197.231
• Product Categories: N-BOC
• Mol File: 657396-97-9.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Carbamic acid, (4-oxo-2-cyclopenten-1-yl)-, 1,1-dimethylethyl ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (4-oxo-2-cyclopenten-1-yl)-, 1,1-dimethylethyl ester (9CI)(657396-97-9)
• EPA Substance Registry System: Carbamic acid, (4-oxo-2-cyclopenten-1-yl)-, 1,1-dimethylethyl ester (9CI)(657396-97-9)

Safety Data

• Hazardous Substances Data: 657396-97-9(Hazardous Substances Data)

Usage

Uses

Used in Pharmaceutical Synthesis:
Carbamic acid, (4-oxo-2-cyclopenten-1-yl)-, 1,1-dimethylethyl ester (9CI) is used as a building block in the synthesis of pharmaceuticals for its potential to contribute to the development of new drugs.
Used in Agrochemical Synthesis:
Carbamic acid, (4-oxo-2-cyclopenten-1-yl)-, 1,1-dimethylethyl ester (9CI) is also used as a building block in the synthesis of agrochemicals, playing a role in the creation of new pesticides or other agricultural products.
It is important to handle and store Carbamic acid, (4-oxo-2-cyclopenten-1-yl)-, 1,1-dimethylethyl ester (9CI) with care, as it may pose health and environmental risks if not managed properly.

Upstream product

• 657396-96-8 (4-hydroxycyclopent-2-enyl)-carbamic acid tert-butyl ester 
• 154802-92-3 (+/-)-1-hydroxy-4-[(tert-butoxycarbonyl)amino]-2-cyclopentene 
• 36016-38-3 tert-Butyl N-hydroxycarbamate 
• 99027-90-4 2-oxa-3-azabicyclo[2.2.1]hept-5-ene-3-carboxylic acidtert-butyl ester 
• 542-92-7 cyclopenta-1,3-diene 
• 24424-99-5 di-tert-butyl dicarbonate 

Relevant articles and documents

Concise synthesis of 4-acylamino analogues of 2-aminobicyclo[3.1.0]hexane- 2,6-dicarboxylic acids (LY354740) from an acylnitroso Diels-Alder cycloadduct

Concise total syntheses of 4-acylamino analogues of LY354740 were accomplished employing an N-Boc acylnitroso Diels-Alder cycloadduct as the starting material. The syntheses involved N-O bond cleavage, oxidation, intermolecular cyclopropanation, Bucherer-

Synthesis of 4-azacyclopent-2-enones and 5,5-dialkyl-4-azacyclopent-2- enones

Three different methods are reported for the preparation of 4-azacyclo-2-enones 1, two of which allow the preparation of the compounds in optically active form. In addition, a facile route to 4-aza-5,5- dimethylcyclopent-2-enones 2 is disclosed.

IMPROVEMENTS IN PHARMACEUTICALLY USEFUL COMPOUNDS

A compound of formula (I) or (II): wherein A is hydrogen or CR1R2; Y and Z are each, independently, hydrogen or a halogen;X is -NR4R5, or R7; R1 is hydrogen, or a substituted or unsubstituted alkyl or alkenyl group containing 1-4 carbon atoms; when X is -NR4R5, R2 is a substituted or unsubstituted alkyl, alkenyl, alkynyl, aryl, aralkyl aralkenyl, or aralkynyl group, that optionally includes at least one heteroatom in its carbon skeleton and contains 1-12 carbon atoms; when X is R7, R2 is an unsubstituted alkyl, alkenyl or alkynyl group, or a substituted or unsubstituted aryl, aralkyl aralkenyl, or aralkynyl group, that optionally includes at least one heteroatom in its carbon skeleton and contains 1-12 carbon atoms; R3 is a substituted or unsubstituted alkyl, alkenyl, alkynyl, aryl, aralkyl aralkenyl, or aralkynyl group, that optionally includes at least one heteroatom in its carbon skeleton and contains 1-12 carbon atoms; R4 is hydrogen, a substituted or unsubstituted alkyl, alkenyl, alkynyl, aryl, aralkyl aralkenyl, or aralkynyl group, that optionally includes at least one heteroatom in its carbon skeleton and contains 1-12 carbon atoms, -COOR8, or -COR8; R5 is hydrogen, or a substituted or unsubstituted alkyl or alkenyl group containing 1-5 carbon atoms; R7 is an unsubstituted alkyl, alkenyl, or alkynyl group, that contains 1-4 carbon atoms; and, R8 is an unsubstituted or halo-substituted alkyl, aryl, or aralkyl group, that contains 1-12 carbon atoms.