657401-93-9

Basic information

• Product Name: Benzeneacetonitrile, alpha-oxo-2-(2-propenyloxy)- (9CI)
• Synonyms: Benzeneacetonitrile, alpha-oxo-2-(2-propenyloxy)- (9CI)
• CAS NO: 657401-93-9
• Molecular Formula: C₁₁H₉NO₂
• Molecular Weight: 187.19466
• Product Categories: METHOXY
• Mol File: 657401-93-9.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzeneacetonitrile, alpha-oxo-2-(2-propenyloxy)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetonitrile, alpha-oxo-2-(2-propenyloxy)- (9CI)(657401-93-9)
• EPA Substance Registry System: Benzeneacetonitrile, alpha-oxo-2-(2-propenyloxy)- (9CI)(657401-93-9)

Safety Data

• Hazardous Substances Data: 657401-93-9(Hazardous Substances Data)

Upstream product

• 28752-82-1 2-(allyloxy)benzaldehyde 
• 89-95-2 2-methyl-benzyl alcohol 

Downstream Products

• 657401-96-2 2-(2-allyloxy-benzoyl)-4-(3-methyl-but-2-enyl)-cyclohexane-1,3-dione 
• 657401-99-5 2-(2-allyloxy-benzoyl)-4,4-bis-(3-methyl-but-2-enyl)-cyclohexane-1,3-dione 
• 657402-01-2 2-(2-allyloxy-benzoyl)-3-methoxy-6-(3-methyl-but-2-enyl)-cyclohex-2-enone 
• 657402-05-6 2-[1-(2-Allyloxy-phenyl)-1-methoxy-meth-(E)-ylidene]-4-(3-methyl-but-2-enyl)-cyclohexane-1,3-dione 
• 657402-04-5 2-(2-allyloxy-benzoyl)-3-methoxy-6,6-bis-(3-methyl-but-2-enyl)-cyclohex-2-enone 
• 657402-08-9 2-[1-(2-Allyloxy-phenyl)-1-methoxy-meth-(E)-ylidene]-4,4-bis-(3-methyl-but-2-enyl)-cyclohexane-1,3-dione 

Relevant articles and documents

Olefin Metathesis: Remote Substituents Governing the Stereoselectivity of 11-Membered-Ring Formation

(Matrix presented) Stereospecific RCM reaction of 7 (R1 = Me) results in the formation of (Z)-11-membered macrocycle 9c. Cascade RCM/ROM/RCM transformation of 7 (R1 = H) affords the thermodynamically more stable spirocycle product 12.