Synthesis of biaryls by intramolecular radical transfer in phosphinates
Phosphinates 20a-35a give biaryls 20b-35b on heating with stannanes in the presence of AIBN. The process involves a radical ipso substitution on the migrating aryl ring.
Clive,Kang
p. 6083 - 6091
(2007/10/03)
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