Polyethylene as a nonvolatile solid cosolvent phase for catalyst separation and recovery
The studies described here show that a relatively low molecular weight, narrow polydispersity polyethylene (PE) wax (Polywax) can serve as a nontoxic and nonvolatile alternative to alkane solvents in monophasic catalytic organic reactions where catalysts
Yang, Yanfei,Priyadarshani, Nilusha,Khamatnurova, Tatyana,Suriboot, Jakkrit,Bergbreiter, David E.
supporting information
p. 14714 - 14717,4
(2020/08/24)
NOVEL METHOD FOR PREPARING STYRENIC OLEFINS
The present invention relates to a method for preparing a styrenic olefin. The method of the present invention comprises the steps of: adding a catalyst and a solvent in a reactor and heating the reactor to create a reflux state; adding an alcohol starting material to the reactor dropwise at a constant rate; removing water generated by adding the alcohol starting material from the reactor; and purifying the obtained styrenic olefin. The method of the present invention is advantageous in minimizing byproducts and preparing styrenic olefins having a variety of substituents in high yield.
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Page/Page column 13
(2008/06/13)
Syndiospecific synthesis of longer p-n-alkyl-substituted polystyrenes using monocyclopentadienyl-type titanium catalysts
Substituted styrenes with linear alkyl substituents (C6 to C12) at the para position on the ring were synthesized and polymerized using the (Me)5CpTi(OMe)3/MAO catalytic system. Increased polymerization activiti
Quirk, Roderic P.,Ok, Myung-Ahn
p. 3976 - 3982
(2007/10/03)
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