- A Novel Nitrone Cycloaddition/ Rearrangement
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Adamantanone-derived nitrone 4 and some other keto-nitrones, when reacted with aromatic and aliphatic aldehydes in refluxing toluene or tetrahydrofuran, formed the corresponding aldonitrones (Z)-10, the latter arising from the fragmentation of an initially formed 1,4,2-dioxazolidine 6 to adamantan-2-one and an oxaziridine intermediate 11, which then rearranges to (Z)-10.
- Toder, Bruce H.,Mullen, George B.,Georgiev, Vassil St.
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p. 169 - 173
(2007/10/02)
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