The endo- and exo-1,7,7-Trimethylbicyclo-heptan-2-amines (Bornan-2-amines) and Their Acetamides
Melting points provide a poor method for differentiation between the exo and endo N-(bornan-2-yl)-acetamides, and have led to errors by previous workers.Spectral differences leading to unambiguous assignment are discussed in this paper.Trapping of the bornan-2-yl carbenium ion with acetonitrile leads to exo products.
Carman, Raymond M.,Greenfield, Kay L.
p. 1785 - 1790
(2007/10/02)
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