Synthesis and characterization of 2-imino-indole nickel complexes and their ethylene oligomerization study
A series of 2-imino-indole derivatives and their neutral nickel complexes were synthesized and characterized. A single-crystal X-ray analysis of [Ni(C10H7)(C18H16ClN 2)(PPh3)] shows the nickel center adopted a square-planar coordination geometry. The nickel complexes act solely as effective catalysts for ethylene oligomerization with the activity up to 2.05 × 10 4 g ethylene mol-1 h-1.
Li, Jitai,Gao, Tielong,Zhang, Wen,Sun, Wen-Hua
p. 1372 - 1374
(2008/10/08)
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