- Photooxidation and 13C N.M.R. Spectroscopic Investigation of 5,6-Dihydrodicyclopentadiene Derivatives
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The sensitized photooxidation of endo-5,6-dihydrodicyclopentadiene (2) by singulet oxygen gives via the corresponding hydroperoxide (10) exo-1-hydroxy-5,6-dihydrodicyclopentadiene (7a).Starting from exo-5,6-dihydrodicyclopentadiene (6) exo-5,6-dihydrodicyclopentadien-1-one (12) is formed.The 13C n.m.r. spectroscopical data of these compounds and of other hydroxy, alkoxy and acyloxy dihydrodicyclopentadiene derivatives are discussed in relation on their structure.
- Fanghaenel, E.,Keita, Y.,Radeglia, R.,Schmidt, W.
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p. 837 - 846
(2007/10/02)
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