Green production of polymer-supported PdNPs: Application to the environmentally benign catalyzed synthesis of cis-3-hexen-1-ol under flow conditions
Pd nanoparticles generated on gel type ion-exchange resins under catalytic conditions show high activity, selectivity and durability in partial hydrogenation reactions under mild conditions, thus providing a green, low-cost option for fine-chemicals production. The application to the continuous-flow synthesis of the leaf alcohol fragrance cis-3-hexen-1-ol is demonstrated.
Heterogeneously catalyzed asymmetric hydrogenation of C=C bonds directed by surface-tethered chiral modifiers
Asymmetric hydrogenation of C=C bonds is of the highest importance in organic synthesis, and such reactions are currently carried out with organometallic homogeneous catalysts. Achieving heterogeneous metal-catalyzed hydrogenation, a highly desirable goal
Watson, David J.,Jesudason, R. J. Bennie Ram John,Beaumont, Simon K.,Kyriakou, Georgios,Burton, Jonathan W.,Lambert, Richard M.
experimental part
p. 14584 - 14589
(2010/03/25)
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