674309-76-3Relevant articles and documents
Ring-expansion protocol: Preparation of synthetically versatile dihydrotropones
Do, Young-Sun,Sun, Ruiying,Kim, Hee Jin,Yeo, Jung Eun,Bae, Sung-Hee,Koo, Sangho
body text, p. 917 - 920 (2009/06/20)
A ring-expansion protocol that consisted of the 1,2-addition of various enolate nucleophiles to 6-trimethylsiloxy-2- cyclohexene-1-one (1) and the NaIO4-promoted oxidative ring opening of the resulting diols 2, followed by an intramolecular Kno
The intramolecular Baylis-Hillman reaction: Easy preparation of versatile substrates, facile reactions, and synthetic applications
Yeo, Jung Eun,Yang, Xiuling,Kim, Hee Jin,Koo, Sangho
, p. 236 - 237 (2007/10/03)
We have developed a general and highly efficient method for the preparation of diverse ω-formyl-aα,β-unsaturated carbonyl compounds and optimized the conditions for the intramolecular Baylis-Hillman reactions of these compounds to provide various biologic
SOME UNUSUAL REACTIONS OF MOLECULAR OXYGEN WITH BICYCLIC DIAZENES WHICH TYPICALLY SERVE AS PRECURSORS TO ALKYLIDENECYCLOPENTANE-1,3-DIYLS; PEROXIDE FORMATION
Little, R. Daniel,Losinski-Dang, Lorraine,Venegas, Manuel G.,Merlic, Craig
, p. 4499 - 4502 (2007/10/02)
The reaction of a series of substituted bicyclic diazenes with oxygen was investigated.Three types of products result, namely ketoalcohols 2b-f, ketoaldehydes 4e-g and dioxolanes 3e-g.The potential intermediacy of an endoperoxide 5f is considered.
