Ordering the reductive and cytochrome P450 oxidative steps in demethylsterigmatocystin formation yields general insights into the biosynthesis of aflatoxin and related fungal metabolites
The biosynthesis of the potent environmental carcinogen aflatoxin B1 involves ca. 15 steps beyond the first polyketide intermediate. Central among these is the rearrangement of the anthraqinone versicolorin A to the xanthone demethylsterigmatocystin. Gene
Henry, Kevin M.,Townsend, Craig A.
p. 3724 - 3733
(2007/10/03)
Reduction of sterigmatocystin and versicolorin A hemiacetals with sodium borohydride
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Chen,Kingston,Vercellotti
p. 3599 - 3605
(2007/10/10)
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