68011-86-9

Basic information

• Product Name: 1-(2-Furanyl)-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane
• Synonyms: 1-(2-Furanyl)-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane
• CAS NO: 68011-86-9
• Molecular Formula: C10H15NO4Si
• Molecular Weight: 241.3159
• Mol File: 68011-86-9.mol

Chemical Properties

• Boiling Point: 257°Cat760mmHg
• Flash Point: 109.3°C
• Appearance: /
• Density: 1.24g/cm³
• Vapor Pressure: 0.0149mmHg at 25°C
• Refractive Index: 1.538
• CAS DataBase Reference: 1-(2-Furanyl)-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-Furanyl)-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane(68011-86-9)
• EPA Substance Registry System: 1-(2-Furanyl)-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane(68011-86-9)

Safety Data

• Hazardous Substances Data: 68011-86-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H15NO4Si/c1-2-10(12-6-1)16-13-7-3-11(4-8-14-16)5-9-15-16/h1-2,6H,3-5,7-9H2

Upstream product

• 55811-52-4 2-furyltriethoxysilane 
• 102-71-6 triethanolamine 
• 1578-45-6 Tetra(2-furanyl)silan 
• 283-56-7 2,8,9-trioxa-5-aza-1-borabicyclo[3.3.3]undecane 

Relevant articles and documents

A novel route to pentacoordinated organylsilanes and -germanes

New convenient methods of sila- and germatranes synthesis from ethoxy- and tetraorganylsilanes and -germanes have been elaborated. The reaction of ethoxysilanes with boratrane in the presence of catalytic amounts of metal alcoholates has been investigated. Dimethylformamide (DMF) as a solvent and NaOEt as a catalyst used instead of xylene and Al(Oi-Pr)3 were found to give better yields. The possibility of using alkoxy-, aminosilanes, tetraethoxygermane and even tetraorganylsilanes in this reaction leading to the corresponding atranes with good yields has been demonstrated. Triethanolamine in the presence of catalytic amounts of base or CsF easily substitutes furyl-, dihydrofuryl-, dihydropyranyl- and thienyl groups in tris- and tetraheterylsilanes, leading to organylsilatranes with good to excellent yields.

Organylsilatranes from the reaction of tetraorganylsilanes with triethanolamine

Triethanolamine selectively cleaves Si-C bonds in heterylsilanes (3) under basic/nucleophilic catalysis, leading to organylsilatranes (4) with good to excellent yields.