Oxidation of aliphatic side chains in anthracene Diels-Alder adducts
An efficient oxidation of methyl and primary side chains of anthracene Diels Alder adducts with KMnO4 is reported. The oxidation leaves the bridgehead methines intact providing Diels-Alder adducts of anthracenecarboxylic acids. Retro Diels-Alder reaction allows for the preparation of the parent anthracenecarboxylic acids.
McCormick, Frankie A.,Marquardt, Donald J.
p. 5169 - 5172
(2007/10/02)
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