- KINETICS OF REACTION OF CHLOROMETHYLALKYL SULFIDE WITH PYRIDINE
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The reaction kinetics of the following sulfides: chloromethyl-n-butyl, chloromethyl-n-pentyl, chloromethyl-n-hexyl and chloromethyl-n-octyl with pyridine in dimethylformamide, cyclohexanone, acetophenone, ethyl acetate, chloroform and cyclohexane have been studied.It has been found that the investigated reactions are the reactions of the first order in relation to sulfide.Further, the rate constants of reactions, activation energies and thermodynamic activation parameters have also been determined.
- Pernak, Juliusz
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p. 439 - 446
(2007/10/02)
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- KINETICS OF SYNTHESIS OF OCTYLTHIOMETHYLPYRIDINIUM CHLORIDE
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Studies have been carried out on kinetics of the synthesis of octylthiomethylpyridinium chloride from chloromethyl-n-octyl thioether and pyridine, 3-methylpyridine, 3,5-dimethylpyridine in N,N-dimethylformamide and in acetone.The reaction was found to be of first order with respect to thioether and zero order with respect to amine.Arrhenius' parameters have been determined.
- Pernak, Juliusz,Walerowicz, Wojciech
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p. 1109 - 1114
(2007/10/02)
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