Utilization of methyl 3-Aryl-2-thiocyanatopropanoates in the synthesis of 2-(4-morpholinyl)- and 2-(piperazinyl)-5-(benzyl)thiazol-4-ones1
By the reaction of methyl acrylate with arenediazonium salts and KSCN in the presence of copper(II) acetate, the methyl 3-aryl-2-thiocyanatopropanoates 2 have been obtained. These compounds react with morpholine or monosubstituted piperazines in the prese
Obushak, Mykola D.,Karpyak, Volodymyr V.,Ostapiuk, Yuri V.,Matiychuk, Vasyl S.
p. 1437 - 1445
(2008/02/08)
SYNTHESIS, ANTIFUNGAL, AND ANTIMICROBIAL PROPERTIES OF 1-THIOCYANATO-1-ALKOXYCARBONYL-2-ARYLETHANES
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Grishchuk, B. D.,Prodanchuk, N. G.,Gorbovoi, P. M.,Nivalov, V. N.,Sinchenko, V. G.
p. 143 - 145
(2007/10/02)
THIOCYANATOARYLATION OF ACRYLIC AND METHACRYLIC ESTERS
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Grishchuk, B. D.,Gorbovoi, P. M.,Ganushchak, N. I.
p. 1668 - 1671
(2007/10/02)
IODOARYLATION OF ACRYLONITRILE AND ACRYLIC ESTERS WITH ARENEDIAZONIUM SALTS
In the reaction of acrylic esters and acrylonitrile with arenediazonium salts in the presence of alkali-metal iodides the products from addition of the aryl radical and iodine at the double bond are formed.An effective method is proposed for the synthesis of 1-iodo-1-methoxycarbonyl(cyano)-2-arylalkanes, which enter readily into nucleophilic substitution of iodine.When boiled with an alcohol solution of alkali, they are transformed into derivatives of cinnamic acid.
Ganushchak, N. I.,Obushak, N. D.,Polishchuk, O. P.
p. 2291 - 2295
(2007/10/02)
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