Highly enantio- and diastereoselective organocatalytic asymmetric domino Michael-Aldol reaction of β-ketoesters and α,β-unsaturated ketones
Three to four contiguous stereogenic centers are formed in the title reaction (see scheme). The optically active cyclohexanones are formed as single diastereomers with excellent enantioselectivities (up to 99% ee) and can be transformed into synthetically
Halland, Nis,Aburel, Pompiliu S.,Jorgensen, Karl Anker
p. 1272 - 1277
(2007/10/03)
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