Vinyl and carbene ruthenium(II) complexes from hydridoruthenium(II) precursors
The reactions of the hydrido compounds [RuHCl(CO)(L)2] {L = PiPr3 (1), PCy3 (2)} with HC≡CR (R = H, Ph, tBu) afforded by insertion of the alkyne into the Ru-H bond the corresponding vinyl complexes [RuCl(CH=CHR)-(CO)(L)su
Jung, Stefan,Brandt, Carsten D.,Wolf, Justin,Werner, Helmut
p. 375 - 383
(2007/10/03)
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