With lower ketones (acetone, methyl ethyl ketone) in weakly acidic solution, flavonoid rhamnosides and rutinosides form alkylidene derivatives at the cis-diol grouping of the rhamnose residue.It has been found that the formation of alkylidene derivatives of flavonoid glycosides is a side reaction that takes place during the chromatographic process on an "acid" polyamide sorbent.
Zapesochnaya, G. G.,Shervashidze, I. V.,Tyukavkina, N. A.
p. 167 - 169
(2007/10/02)
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