THE MECHANISM OF HYDROXYLATION OF ORGANOMETALLIC REAGENTS BY 2-SULFONYLOXAZIRIDINES
The hydroxylation of organometallic reagents (RM) by 2-sulfonyloxaziridines 1 is shown to involve a hemiaminal intermediate 2, whose stability is apparently related to the nucleophilicity of the hydroxylated product (ROH).
Davis, Franklin A.,Wei, Jia,Sheppard, Aurelia C.,Gubernick, Steven
p. 5115 - 5118
(2007/10/02)
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