Remarkable levels of enantioswitching in catalytic asymmetric hydroboration
TADDOL-derived phosphites and phosphoramidites are effective ligands for rhodium-catalyzed asymmetric hydroborations of β,γ-unsaturated amides, achieving up to 99% ee. However, the sense of stereoinduction, R or S, is surprisingly dependent on rather subt
Smith, Sean M.,Takacs, James M.
supporting information; experimental part
p. 4612 - 4615
(2010/12/19)
DISPROPORTIONATION OF TETRASUBSTITUTED PHOSPHORODIAMIDOUS CHLORIDES
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Marchenko, A. P.,Kovenya, V. A.,Kudryavtsev, A. A.,Pinchuk, A. M.