Facile synthesis of simple mono-alkyl phosphates from phosphoric acid and alcohols
Simple aliphatic alcohols can be selectively converted into mono-alkyl phosphate esters at the laboratory scale using the acetic anhydride-mediated activation of inorganic phosphate.
Dueymes, Cyril,Pirat, Céline,Pascal, Robert
p. 5300 - 5301
(2008/12/22)
UNE METHODE SIMPLE DE SYNTHESE DES PHOSPHATES TERPENIQUES ALLYLIQUES PRIMAIRES ET TERTIAIRES.
Alkylation of tetrabutylammonium dihydrogenophosphate by terpenic allylic sulphonium salts give the corresponding primary terpenic allylic phosphates in fair to moderate yields, without complex procedures of purification.The catalysis of the reaction by cuprous ion leads to the isolation of tertiary allylic phosphates.
Julia, M,Mestdagh, H.,Rolando, C.
p. 3841 - 3850
(2007/10/02)
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