Aryl group - A leaving group in arylphosphine oxides
The treatment of triphenylphosphine oxide with organometallic reagents leads to the substitution of up to three phenyl substituents with the incoming carbon nucleophile. The replacement of the phenyl/aryl group in tertiary diarylalkylphosphine oxides or even aryldialkylphosphine oxides was also observed. Naphthyl-substituted phosphine oxides undergo Michael-type addition at the naphthyl group when treated with organolithium reagent.
Stankevi?, Marek,Pisklak, Jolanta,W?odarczyk, Katarzyna
p. 810 - 824
(2016/01/20)
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