REACTIONS OF O,O-DIALKYL HYDROGEN PHOSPHOROTHIOATES WITH NITRILES AND THIOCYANATES
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Zimin, M. G.,Zabirov, N. G.,Kamalov, R. M.,Pudovik, A. N.
p. 2353 - 2358
(2007/10/02)
STUDIES ON ORGANOPHOSPHORUS COMPOUNDS PART 55 THE TRANSFORMATION OF NITRILES TO THIOAMIDES WITH O,O-DIALKYLDITHIOPHOSPHORIC ACID
The reaction between nitriles and O,O-dialkyldithiophosphoric acid (2) under anhydrous conditions produces O,O-diethyl-N-thiobenzoylamidophosphate (5), contrary to literature.When water is present the same reaction gives the corresponding thioamides in reasonable to good yields.Mechanistic considerations and spectral data are presented for the products.
Shabana, R.,Meyer, H.J.,Lawesson, S.-O.
p. 297 - 306
(2007/10/02)
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