- COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND AN ELECTRONIC DEVICE THEREOF
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The compound is represented by chemical formula 1. 1 Is a cross-sectional view of an organic electronic device including an organic material layer between the first electrode, the first 2 electrode and the first 1 electrode, and 2. A compound represented
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Paragraph 0152; 0160-0162
(2020/11/28)
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- Structure-property relationships for tailoring phenoxazines as reducing photoredox catalysts
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Through the study of structure-property relationships using a combination of experimental and computational analyses, a number of phenoxazine derivatives have been developed as visible light absorbing, organic photoredox catalysts (PCs) with excited state reduction potentials rivaling those of highly reducing transition metal PCs. Time-dependent density functional theory (TD-DFT) computational modeling of the photoexcitation of N-aryl and core modified phenoxazines guided the design of PCs with absorption profiles in the visible regime. In accordance with our previous work with N,N-diaryl dihydrophenazines, characterization of noncore modified N-aryl phenoxazines in the excited state demonstrated that the nature of the N-aryl substituent dictates the ability of the PC to access a charge transfer excited state. However, our current analysis of core modified phenoxazines revealed that these molecules can access a different type of CT excited state which we posit involves a core substituent as the electron acceptor. Modification of the core of phenoxazine derivatives with electron-donating and electron-withdrawing substituents was used to alter triplet energies, excited state reduction potentials, and oxidation potentials of the phenoxazine derivatives. The catalytic activity of these molecules was explored using organocatalyzed atom transfer radical polymerization (O-ATRP) for the synthesis of poly(methyl methacrylate) (PMMA) using white light irradiation. All of the derivatives were determined to be suitable PCs for O-ATRP as indicated by a linear growth of polymer molecular weight as a function of monomer conversion and the ability to synthesize PMMA with moderate to low dispersity (dispersity less than or equal to 1.5) and initiator efficiencies typically greater than 70% at high conversions. However, only PCs that exhibit strong absorption of visible light and strong triplet excited state reduction potentials maintain control over the polymerization during the entire course of the reaction. The structure-property relationships established here will enable the application of these organic PCs for O-ATRP and other photoredox-catalyzed small molecule and polymer syntheses.
- McCarthy, Blaine G.,Pearson, Ryan M.,Lim, Chern-Hooi,Sartor, Steven M.,Damrauer, Niels H.,Miyake, Garret M.
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supporting information
p. 5088 - 5101
(2018/04/24)
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- Organic micromolecule material based on 2,6-dimethyl-4-cyanophenyl receptor unit, preparation and application
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The invention belongs to the technical field of organic photoelectric materials, and discloses an organic micromolecule material based on a 2,6-dimethyl-4-cyanophenyl receptor unit, preparation and application. The organic micromolecule material has a structural formula as shown in formula (I), and Ar in the formula shows a phenyl aromatic amine heterocycle or phenyl aromatic amine donor unit. Thematerial has a weak intramolecular charge transfer state, and thus, fluorescence emission of a zone from dark blue to ultraviolet can be realized. Meanwhile, because the molecules have quite short effective conjugated length, the material has high triplet state energy level. In the application of an organic electroluminescent device, the problem of unbalanced charge carriers of a unipolar organicphotoelectric material can be solved effectively, therefore, the structure of the device is simplified, and the performance of the device is improved.
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Paragraph 0028; 0032; 0033
(2018/10/19)
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- Organic small molecule luminescent material and organic electroluminescent device prepared from same
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The invention belongs to the field of organic photoelectric material technology, and discloses an organic small molecule luminescent material and an organic electroluminescent device prepared from same. The organic small molecule luminescent material uses
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- Compound For Organic Optoelectronic Device, Organic Light Emitting Diode Including The Same and Display Including The Organic Light Emitting Diode
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Compound for organic optoelectronic devices, including organic luminous person element and same said device relates to display including organic light emitting device, an organic optoelectronic device represented by formula 1 a provided is a compound for the, excellent electrochemical and thermal stability and and excellent life characteristics, low, even under a low drive voltage optoelectronic devices additive is soluble in the organic monomer a high luminous efficiency can be produced. [Formula 1] Specification the present definition of said formula 1 is described.
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Paragraph 0804-0808
(2016/11/24)
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- COMPOUND FOR ORGANIC OPTOELECTRONIC DEVICE, ORGANIC LIGHT EMITTING DIODE INCLUDING THE SAME AND DISPLAY INCLUDING THE ORGANIC LIGHT EMITTING DIODE
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Compound for organic optoelectronic devices, including organic luminous person element and same said device relates to display including organic light emitting device, an organic optoelectronic device represented by formula 1 a provided is a compound for the, excellent electrochemical and thermal stability and and excellent life characteristics, low, even under a low drive voltage optoelectronic devices additive is soluble in the organic monomer a high luminous efficiency can be produced. [Formula 1] Specification the present definition of said formula 1 is described.
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Paragraph 0797-0800
(2016/10/10)
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- Bromination of 10-Phenylphenothiazine and 10-Phenylphenoxazine
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The reaction of either 10-phenylphenothiazine (1) with bromine in acetic acid or the cation radical of 1 with bromide ion gives ring substitution only and in accord with customary stoichiometry for nucleophilic substitution of aromatic cation radicals.However, the reaction of 1 with pyridinium bromide perbromide (2) gives predominantly 10-phenyl ring substitution and a small amount of ring substitution products.Evidence is presented which indicates that ring substitution occurs via cation radical whereas 10-phenyl substitution proceeds via electrophilic attack on the neutral molecule 1.Substitution of 10-phenylphenoxazine (4) occurs predominantly but not exclusively on the phenoxazine ring; some bromination does occur on the 10-phenyl ring.In contrast, the reaction of 4 with bromine gives only ring mono- and disubstitution products.These results indicate that both 1 and 4 react similarly under the same conditions.
- Jovanovic, Misa V.,Biehl, Edward R.
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p. 1905 - 1908
(2007/10/02)
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