Hydrocarbonylating Cyclization of Dienes, 6. - Metal-Induced Skeletal Rearrangements during an Attempted Synthesis of the Acorane System from Substituted 1,1-Divinylcyclohexanes
In attempts of a regio- and stereoselective synthesis of the acorane skeleton 2, substituted 1,1-divinylcyclohexanes 1 were treated under the conditions of hydrocarbonylating cyclization.Substrates with higher degree of substitution surprisingly did not l