NUCLEOPHILIC SUBSTITUTION OF α-ALLENIC ALCOHOLS VIA THE MURAHASHI METHOD: 1,3-DIENES SYNTHESIS.
The alkylation of α-allenic alcohols 1 by the Murahashi procedure leads to 1,3-dienes 4.This process allows the direct nucleophilic substitution of labile or hindered α-allenic alcohols by organolithium reagents.
Fan, Changlie,Cazes, Bernard
p. 1701 - 1704
(2007/10/02)
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