Anti-Markovnikov rearrangement in sulfur mediated allylic C-H amination of olefins
Cationic rearrangement reactions usually follow Markovnikov's rule to give more substituted carbocations as stable intermediates. During our study on sulfur mediated allylic C-H amination of olefins, very rare cases of anti-Markovnikov rearrangement from secondary carbocations toward primary carbocations or primary triflates were observed.
Zhang, Zhong,Du, Hongguang,Xu, Jiaxi,Li, Pingfan
supporting information
p. 11547 - 11550
(2016/10/03)
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