Enantioselective Syntheses of Aldols and Homoallylic Alcohols from 1,3-Dioxolan-4-ones Using Mandelic Acid as Chiral Auxiliary
The 1,3-dioxolan-4-ones obtained by condensation of (S)-(+)- or (R)-(-)-mandelic acid with aldehydes and ketones react under electrophilic conditions cleanly and with reasonable diastereoselectivities with enol silyl ethers or allylsilanes.The chiral auxi
Mashraqui, Sabir H.,Kellogg, Richard M.
p. 2513 - 2516
(2007/10/02)
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