72293-97-1Relevant articles and documents
Facile and selective deprotection of PMB ethers and esters using oxalyl chloride
Ilangovan, Andivelu,Anandhan, Karnambaram,Kaushik, Mahabir Prasad
supporting information, p. 1081 - 1084 (2015/02/19)
Oxalyl chloride, (0.5 equiv) was found to cleave the PMB group from alkyl, aryl PMB ethers, and esters to give corresponding alcohol and acid in good yields. This method offers simple and efficient protocol for the selective deprotection of PMB ether and ester in DCE at ambient temperature.
Total synthesis of natural p -quinol cochinchinenone
Barradas, Silvia,Hernández-Torres, Gloria,Urbano, Antonio,Carre?o, M. Carmen
supporting information, p. 5952 - 5955 (2013/02/23)
Cochinchinenone has been synthesized in only five steps and four pots and in 58% overall yield from commercially available 2,3-dimethoxy-4-hydroxy- benzaldehyde and OPMB-protected p-hydroxy acetophenone, the key step being the oxone-mediated oxidative dea
Synthesis of several benzyloxphenyl derivatives with local anesthetic activity (author's transl)
Rudinger-Adler,Buechi
, p. 1326 - 1331 (2007/10/04)
Several 2- and 4-benzyloxy- and 4-(2'- and 4'-substituted) benzyloxy-beta-substituted amino-propiophenones, some of the corresponding alcohols, some 4-benzyloxy-alpha-substituted amino-acetophenones were synthetised and tested for their pharmacological activity.