Synthetic Microbial Chemistry, XVII. Synthesis of the Complement Inhibitor (-)-K-76 and of Related Compounds
The complement inhibitor (-)-K-76 (1) was synthesized starting from (S)-3-hydroxy-2,2-dimethylcyclohexanone (3) employing dihydroxy sesquiterpene ester 2 as the key intermediate.The diastereomer 26 of 2 yielded the β-diol isomer 49 of (-)-K-76, and 26' ga
Mori, Kenji,Komatsu, Makoto
p. 107 - 120
(2007/10/02)
Total Synthesis of the Complement Inhibitor K-76 in Racemic Form. Structural Assignment to "K-76 Monocarboxylic Acid"
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Corey, E. J.,Das, Jagabandhu
p. 5551 - 5553
(2007/10/02)
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