733035-90-0Relevant articles and documents
Process for preparing alkynyl-substituted aromatic and heterocyclic compounds
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Page/Page column 11, (2010/02/12)
Mono- and disubstituted aryl or heterocyclic acetylenes are produced by a process comprising reacting an aryl nitrile with an alkynylzinc compound, a bis-alkynylzinc compound, or an alkynylmagnesium compound, in the presence of a nickel/phosphine catalyst.
Alkynylation of benzonitriles via nickel catalyzed C-C bond activation
Penney, Jonathan M.,Miller, Joseph A.
, p. 4989 - 4992 (2007/10/03)
The scope of synthetically useful nickel catalyzed cross coupling reactions of benzonitriles has now been expanded to allow alkynylation. Thus, the cross coupling of benzonitriles with alkynylzinc reagents occurs readily in the presence of Ni/PMe3/s