A radical-organometallic glycine synthon. Preparation of homochiral heterocyclic α-amino acids
Co(Acac)2 reacts with (1) and (d)-menthyl N-BOC-2-bromoglycinates to give (1)- and (d)-menthyl N-BOC-3-acetylnorvalinates, which are converted into homochiral 2-(3,5-dimethyl-4-pyrazolyl)glycine and 2-(3,5-dimethyl)-4-isoxazolylglycine.
Lloris,Moreno-Manas
p. 7119 - 7122
(2007/10/02)
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