- A NOVEL FORM OF SULFOMETURON METHYL, A PROCESS FOR ITS PREPARATION AND USE THE SAME
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A new crystalline form of sulfometuron methyl of formula (I), the crystal preparation process, the analyses of the crystal through various analytical methods and using the crystal to prepare stable agrochemical formulation. The invention also describes the use of various solvents towards the crystalline form preparation conditions. The novel crystal form is particularly suitable for use in herbicidal compositions and in the control of unwanted plant growth.
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Page/Page column 15-16
(2020/03/23)
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- A 2 - (4,6-dimethyl-pyrimidin-2-yl-carbamoyl amino sulfonyl) benzoic acid synthesis of methyl
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The invention discloses a synthetic method of 2-(4, 6-dimethyl pyrimidine-2-base amino formyl amino sulfonyl) methyl benzoate. The method is characterized in that gluside and dimethyl carbonate are adopted for preparing an intermediate of N-methyl formate-o-sulfonylbenzoylimine, and then methanol is adopted for preparing an intermediate of o-methoxy carboxide benzenesulfonamide methyl formate. The purity of 2-(4,6-dimethyl pyrimidine-2-base amino formyl amino sulfonyl) methyl benzoate prepared by the synthetic method provided by the invention reaches more than 95.0%, and the total yield reaches 55.0%. The method is mainly applied to preparation of 2-(4, 6-dimethyl pyrimidine-2-base amino formyl amino sulfonyl) methyl benzoate and has the advantages that raw materials are cheap and easy to obtain, the technology is simple, the three wastes are few, virulent suffocating gas is prevented from being used, and the method is suitable for batch industrialized production.
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Paragraph 0046; 0069; 0070
(2016/10/07)
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- Halopyridyl triazolinone herbicides and herbicidal use thereof
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Disclosed are herbicidal halopyridyl triazolinones, herbicidal compositions comprising the halopyridyl triazolinones, and herbicidal use of the compounds and compositions. Such compounds and compositions are useful as both preemergence and postemergence herbicides in a variety of crops.
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- Soybean plants with dominant selectable trait for herbicide resistance
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The utilization of a positive selection seed screening process to isolate rate variants with resistance to a herbicide is described. The ability to screen large numbers of mutagenized seed has made it feasible to pursue and isolate plants with low frequency dominant herbicide-resistance mutations. The dominant herbicide resistance mutations are useful for many applications including expanding the utility of sulfonylurea herbicides for soybean weed control, production of F1 and F2 seeds, and as selectable markers for efficient seed purification.
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- Nucleic acid fragment encoding herbicide resistant plant acetolactate synthase
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A nucleic acid fragment encoding a herbicide-resistant plant acetolactate synthase protein is disclosed. This nucleic acid fragment contains at least one nucleotide mutation resulting in one amino acid change in one of seven substantially conserved regions of acetolactate synthase amino acid homology. This mutation results in the production of an acetolactate synthase protein which is resistant to sulfonylurea herbicide compounds compared to the wild-type protein. Transformation of herbicide sensitive plants or plant cells with the fragment results in resistance to the herbicide.
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- Herbicidal compound concentrate
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There is provided a novel herbicidal compound concentrate in the form of compressed solid formulations that disintegrate in water to form a sprayable dispersion.
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- Agricultural sulfonamides
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N-(heterocyclicaminocarbonyl)arylsulfonamides in which the aryl radical is substituted in the 2-position by a carboxy radical, ester, thioester, or amide thereof; e.g. N-[(4,6-dimethylpyrimidin-2-yl)-aminocarbonyl]-2-methoxycarbonylbenzenesulfonamide or N-[(4,6-dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl]-2-methoxycarbonylbenzenesulfonamide; are useful for the regulation of plant growth and as pre-emergence and post-emergence herbicides.
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- Herbicidal complexes with ureas
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Water-soluble complexes, which have herbicidal utility, can be formed from urea and alkali metal salts of selected sulfonylureas, e.g., chlorsulfuron.
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- Process for preparing sulfonylureas
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Sulfonylureas are prepared by contacting a sulfonyl halide with an ammonium, phosphonium, sulfonium, or an alkali metal cyanate salt in the presence of an amine.
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- Agricultural sulfonamides
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N-(heterocyclicaminocarbonyl)arylsulfonamides in which the aryl radical is substituted in the 2-position by a carboxy radical, ester, thioester, or amide thereof; e.g. N-[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]-2-methoxycarbonylbenzenesulfonamide or N-[(4,6-dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl]-2-methoxycarbonylbenzenesulfonamide; are useful for the regulation of plant growth and as pre-emergence and post-emergence herbicides.
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- Intermediates for herbicidal sulfonamides
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This invention relates to novel o-carbonylbenzenesulfonyl isocyanates and their use as intermediates for the preparation of sulfonylureas which are known to be active herbicides.
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