The .BH4 Radical: an Electron Spin Resonance Study of the Radiolysis of NaBH4
Exposure of NaBH4(NaBD4) to 60Co γ-rays at 77 K gave a species having a large proton hyperfine coupling to two equivalent protons (deuterons), and a small coupling to two other protons (deuterons), together with a strongly anisotropic coupling to 11B.
Symons, Martyn C. R.,Chen, Tsing,Glidewell, Christopher
Infrared spectrum of the novel electron-deficient BH4 radical in solid neon
Laser-ablated boron reacts with hydrogen on condensation in excess neon to give BH4 radical, BH4- anion, and B2H6 as the major products. Identifications are based on 10B and D substitution,
Andrews, Lester,Wang, Xuefeng
p. 7280 - 7281
(2007/10/03)
Oxidation Intermediates of Borohydride and Tetraphenylborate Ions in Aqueous Solutions obtained by Pulse Radiolysis
Absorption spectra of one-electron oxidized intermediates (the H4B and the Ph4B radicals) were observed upon the oxidation of H4B(1-) and Ph4B(1-) by the azide radical (N3), Br2(1-), or (SCN)2(1-) in pulse-irradiated solutions; the spectra
Horii, Hideo,Taniguchi, Setsuo
p. 915 - 916
(2007/10/02)
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