Cycloelimination of β-Silylethyl Sulphoxides: Alkene, Alkyne, and Vinylsilane-forming Reactions
The cycloelimination (1)->(3) of trimethylsilyl sulphenate from a β-silylethyl sulphoxide is slightly faster than the corresponding cycloelimination (2)->(3) of sulphenic acid itself.The former type of reaction can be used to form acetylenes (
Fleming, Ian,Goldhill, Jon,Perry, David A.
p. 1563 - 1570
(2007/10/02)
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