Regiochemical Control of the Addition of Aryl Selenols and Aryl Thiols to the Triple Bond of Arylpropiolates. Synthesis of Seleno- and Thioflavones and Seleno- and Thioaurones
Addition of aryl selenols and aryl thiols to arylpropiolates under basic conditions followed by saponification gave exclusively β-substituted cinnamates of predominant Z sterochemistry.Neat solutions of aryl selenols or aryl thiols and arylpropiolates aft
Wadsworth, Donald H.,Detty, Michael R.
p. 4611 - 4615
(2007/10/02)
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