- (7-Silanorbornadienyl)cyclopentadienyldicarbonyliron complexes: An approach to iron-substituted silylenes
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(7-Methyl-7-silanorbornadienyl)FeCp(CO)2 complexes were prepared from the corresponding silole-iron complexes by Diels-Alder reaction with dimethyl acetylenedicarboxylate or benzyne. Thermolysis of the dimethyl acetylenedicarboxylate adduct in
- Marinetti-Mignani, Angela,West, Robert
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p. 141 - 144
(2008/10/08)
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- HIGH PRESSURE APPROACH TO THE SYNTHESIS OF 7-PHOSPHANORBORNADIENES FORM λ5-PHOSPHOLE OXIDES AND DIALKYL ACETYLENEDICARBOXYLATES
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Reactions of 1,2,3,4,5-pentaphenylphosphole oxide (4a) with dimethyl and di-t-butyl acetylenedicarboxylates (5a, b) under high pressure afford the tetraphenylphthalates (7a, b) along with the 7-phosphanorbornadiene derivatives (6a, b).The latter adducts h
- Matsumoto, Kiyoshi,Hashimoto, Shiro,Otani, Shinichi
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p. 2713 - 2717
(2007/10/02)
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