- Selective dendritic fluorescent sensors for Zn(II)
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A series of dendritic 8-hydroxyquinoline (8-HQ) and 5-dialkyl(aryl) aminomethyl -8-HQ derivatives were synthesized and their fluoroionophoric properties toward representative alkali, alkaline earth, group IIIA and transition metal ions were investigated. Among the selected ions, Zn(II) enhanced the fluorescence of N-di-(methoxycarbonylethyl)aminoethyl-3-[4-(8- hydroxyquinolin-5-ylmethyl)piperazin-1-yl]-propanoic amide] (7) by 31-fold, while Al(III) caused enhancement to some extent. The absence of any significant fluorescence enhancement by the other ions examined renders 7 a highly useful Zn(II)-selective fluorescent sensor.
- Wang, Feng,Peng, Ruogu,Sha, Yaowu
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p. 922 - 930
(2008/09/18)
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- Synthesis of 5-dialkyl(aryl)aminomethyl-8-hydroxyquinoline dansylates as selective fluorescent sensors for Fe3+
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A series of 5-dialkyl(aryl)aminomethyl□-8-hydroxyquinoline dansylates were synthesized and their fluoroionophoric properties toward representative alkali ions, alkaline earth ions and transition metal ions were investigated. Among the selected ions, Fe3+ caused considerable quenching of the fluorescence, while Cr3+ caused quenching to some extent. The absence of any significant fluorescence quenching effects of the other ions examined, especially Fe2+, renders these compounds highly useful Fe 3+-selective fluorescent sensors.
- Peng, Ruogu,Wang, Feng,Sha, Yaowu
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p. 1191 - 1201
(2008/02/07)
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