75851-47-7Relevant articles and documents
A Reinvestigation of the Mechanism of Pseudomonas testosteroni Δ5-3-Ketosteroid Isomerase
Viger, Antoinette,Coustal, Suzy,Marquet, Andree
, p. 451 - 458 (2007/10/02)
The mechanism of isomerization of Δ5-3-keto steroid by the enzyme of P. testosteroni has been reinvestigated with androst-5-ene-3,17-dione 1.The formerly proposed 4β -> 6β intramolecular transfer does not account for all the reaction.It has bee