- Transition-Metal-Free Synthesis of 1,2-diphenyl-1H-benzo[d] Imidazole Derivatives from N-phenylbenzimidamides and Cyclohexanones
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A transition-metal-free strategy for the formation of 1,2-diphenyl-1H-benzo[d] imidazoles from N-phenylbenzimidamides and cyclohexanones is introduced. This is the first report on the direct synthesis of 1,2-diphenyl-1H-benzo[d] imidazoles from cyclohexanones and N-phenylbenzimidamides via iodine- promoted oxidative cyclization. Non-aromatic cyclohexanones were smoothly dehydrogenated, and acted as an aryl source using oxygen as a green oxidant. The catalytic use of iodine makes this method quite simple, more economical and convenient. Under optimized conditions, various substituted 1,2-diphenyl-1H-benzo[d] imidazoles were smoothly reacted, and the desired substituted imidazoles were generated with moderate to excellent yields. (Figure presented.).
- Lu, Guoqiang,Luo, Nan,Hu, Fangpeng,Ban, Zihui,Zhan, Zhenzhen,Huang, Guo-Sheng
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supporting information
p. 487 - 492
(2019/12/12)
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- Substituted 1,3,5-triazine compound, composition and application thereof
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The invention discloses a substituted 1,3,5-triazine compound, a composition and application thereof. The 1,3,5-triazine compound shown as a formula I is provided by the invention, can be used as an electron transport material and, can be used as an electron acceptor material. The composition that can be used for preparing an electron transport layer or an electron donor material is used as a mainbody material of an electroluminescent device, so that the prepared electroluminescent device has the advantages of relatively high efficiency, relatively long service lifetime and the like. As the 1,3,5-triazine compound is used as an electron transport layer, the composition used as an electron acceptor material and an electron donor material is adopted to construct a light-emitting layer, andthe prepared electroluminescent device has the advantages of higher efficiency, longer service lifetime and the like.
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Paragraph 0221; 0224
(2020/10/16)
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- Bipyridyl derivative and application thereof
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The present invention provides a novel compound, which has a structure general formula represented by a formula (I), wherein Ar1 and Ar2 are independently selected from an aromatic hydrocarbon derivative group containing benzimidazoyl, an aromatic hydrocarbon derivative group containing a pyridine group, substituted or unsubstituted C6-C30 aromatic hydrocarbon, and a substituted or unsubstituted C6-C30 fused ring aromatic hydrocarbon group, and R1 and R2 are independently and respectively selected from H, C1-C12 aliphatic hydrocarbon radical, phenyl, substituted phenyl, naphthyl, substituted naphthyl, biphenyl and substituted biphenyl. According to the present invention, the compound has characteristics of stable character, simple preparation process, high luminous efficiency and high carrier mobility, and can be used for the electron transport layer of the electroluminescent element, and the device applying the compound has characteristics of significant driving voltage reducing and current efficiency improving. The formula (I) is defined in the instruction.
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- Compound for organic optoelectronic device, organic light emitting diode including the same and display including the organic light emitting diode
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A compound for an organic optoelectronic device is represented by Chemical Formula 1: and, in Chemical Formula 1, one of Ar1 or Ar2 is a substituted or unsubstituted C6 to C30 aryl group, or a substituted or unsubstituted C3 to C30 heteroaryl group, and the other of Ar1 or Ar2 is a substituent represented by the Chemical Formula 2:
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- Boron-containig benzopyrenes derivatives, their preparation and organic electroluminescent device (by machine translation)
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The present invention relates to a 6-tritolyl-6H-6-bora benzo[cd]pyrene derivative represented by a formula (1), wherein substituents are described in an instruction. The present invention further relates to uses of the compound as an electron transportation material, and an organic electroluminescent device containing the compound. Formula (1).
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- 6,12-DINAPHTHYLCHRYSENE DERIVATIVE AND ORGANIC LIGHT-EMITTING DEVICE USING THE DERIVATIVE
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Provided are an organic compound having high heat stability suitable for use in an organic light-emitting device, and an organic light-emitting device using the organic compound. The organic light-emitting device is an organic light-emitting device, including: an anode; a cathode; and an organic compound layer disposed between the anode and the cathode, in which at least one layer of the organic compound layer has a 6,12-dinaphthylchrysene derivative represented by one of the following general formulae (1) and (2): in the formulae (1) and (2), Z represents a naphthyl group, and Q represents an electron-withdrawing substituent selected from the group consisting of the following general formulae (3) to (5): in the formula (5), R 1 represents a hydrogen atom or a methyl group.
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Paragraph 0128-0131
(2016/11/21)
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- Binaphthalene bridged bipolar transporting materials for blue electroluminescence: Toward high EL efficiency via molecular tuning
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Two isomeric bipolar transporting molecules containing arylamine and benzimidazole moieties linked by 1,1-binaphthalene bridge have been synthesized and used for blue light-emitting diodes. The highly twisted binaphthalene bridge is beneficial for amorphous morphology, good solubility, high thermal stability and high photoluminescence quantum efficiency (ΦPL). The charge transfer bands of these compounds exhibit interesting solvent-polarity dependent fluorescence properties. The physical properties of the compounds were tunable upon binding of the benzimidazole with binaphthalene group via C- (BINAPC) or N- (BINAPN) linkage. Three-layered blue-emitting OLEDs using BINAPC or BINAPN as the emitting layer, NPB as the hole transporting layer, and TPBI as the electron transporting layer as well as hole-blocking layer exhibit good performance. External quantum efficiencies of 2.49% with color coordinates of (0.15, 0.11) and 2.67% with color coordinates of (0.16, 0.16) were achieved for BINAPC and BINAPN, respectively.
- Muangpaisal, Rossatorn,Hung, Wei-I.,Lin, Jiann T.,Ting, San-Yu,Chen, Li-Yin
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p. 2992 - 2998
(2014/04/17)
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- NOVEL FUSED POLYCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE, DISPLAY APPARATUS, IMAGE INFORMATION PROCESSING APPARATUS, LIGHTING SYSTEM, AND IMAGE FORMING APPARATUS HAVING THE COMPOUND
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A novel organic compound suitable for blue-light-emitting devices and an organic light-emitting device including the compound are provided. An organic compound represented by Formula [1] according to Claim 1 is provided. In Formula [1], R1 to R16 each independently represent a group selected from a hydrogen atom, a cyano group, substituted or unsubstituted alkyl groups, substituted or unsubstituted aryl groups, and substituted or unsubstituted heterocyclic groups.
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Paragraph 0173-0174
(2014/03/21)
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- "All-water" one-pot diverse synthesis of 1,2-disubstituted benzimidazoles: Hydrogen bond driven 'synergistic electrophile-nucleophile dual activation' by water
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A new "all-water" tandem arylaminoarylation/arylaminoalkylation- reduction-cyclisation route is reported for one-pot diversity oriented synthesis of regiodefined 1,2-disubstituted benzimidazoles. Water plays a crucial and indispensable role through hydrogen bond driven 'synergistic electrophile-nucleophile dual activation' in the formation of N-mono-aryl/aryl alkyl/alkyl/cycloalkyl o-nitroanilines under metal and base-free conditions to replace the transition metal-based C-N bond formation (aryl amination) chemistry and underlines the origin of regiodefined installation of the diverse selection of aryl, aryl alkyl, and alkyl/cycloalkyl groups as substituents on the benzimidazole scaffold to form the 1,2-disubstituted benzimidazoles. The influence of the hydrogen bond effect of water in promoting the arylaminoarylation reaction under base and metal-free conditions has been realized through observation of inferior yields in D2O compared to that obtained in water during the reaction of o-fluoronitrobenzene with aniline separately performed in water and D2O under similar experimental conditions. Water also provides assistance in promoting the subsequent nitro reduction and in the final cyclocondensation steps. The role of water in promoting the cyclocondensation reaction through hydrogen bonds is realized by the differential product yields during the reaction of mono-N-phenyl-o- phenylenediamine with benzaldehyde performed separately in water and D 2O. The better hydrogen bond donor and hydrogen bond acceptor abilities of water compared to those of the organic solvents are the contributing/deciding factors for making the new water-assisted tandem arylaminoarylation/arylaminoalkylation-reduction-cyclisation strategy for the diversified synthesis of the regiodefined 1,2-disubstituted benzimidazoles effective in an aqueous medium, making it represent a true "all-water chemistry."
- Kommi, Damodara N.,Jadhavar, Pradeep S.,Kumar, Dinesh,Chakraborti, Asit K.
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p. 798 - 810
(2013/04/24)
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- Enhancing the luminescence properties and stability of cationic iridium(iii) complexes based on phenylbenzoimidazole ligand: A combined experimental and theoretical study
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Herein we designed and synthesized a series of cationic iridium(iii) complexes with a phenylbenzoimidazole-based cyclometalated ligand, containing different numbers of carbazole moieties from zero to three (complexes 1-4). The photophysical and electroche
- Shan, Guo-Gang,Li, Hai-Bin,Sun, Hai-Zhu,Cao, Hong-Tao,Zhu, Dong-Xia,Su, Zhong-Min
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supporting information
p. 11056 - 11065
(2013/08/23)
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- NITROGENATED HETEROCYCLIC RING DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT COMPRISING SAME
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A nitrogen-containing heterocyclic derivative represented by the following formula (1): wherein any "12-a" groups of R1 to R12 are independently a hydrogen atom, a fluorine atom, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms or a substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms; any "a" groups of R1 to R12 are independently a single bond which is bonded to L1; L1 is a single bond, a "b+1" valent substituted or unsubstituted hydrocarbon ring group having 6 to 30 ring carbon atoms or a "b+1" valent substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms; HAr is a substituted or unsubstituted nitrogen-containing heterocyclic group; and "a" and "b" are independently an integer of 1 to 4, and at least one of "a" and "b" is 1. Also disclosed is a nitrogen-containing heterocyclic derivative represented by the following formula (21) or (31):
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- Fused polycyclic compound and organic light-emitting device using the compound
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Provided are fused polycyclic compounds suitable for use mainly as a component for a blue-light-emitting device, and an organic light-emitting device using the compound. The fused polycyclic compounds are represented by the general formulae (1), (2), (8) and (9).
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Page/Page column 28-29
(2012/12/14)
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- A carbazole-phenylbenzimidazole hybrid bipolar universal host for high efficiency RGB and white PhOLEDs with high chromatic stability
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A novel bipolar molecule CNBzIm comprised of electron-donating carbazole and electron-accepting phenylbenzimidazole is designed, synthesized and characterized for RGB phosphorescent organic light emitting diodes (PhOLEDs). CNBzIm exhibits promising proper
- Hung, Wen-Yi,Chi, Liang-Chen,Chen, Wei-Jiun,Mondal, Ejabul,Chou, Shu-Hua,Wong, Ken-Tsung,Chi, Yun
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body text
p. 19249 - 19256
(2012/02/02)
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- NITROGENOUS HETEROCYCLE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT EMPLOYING THE SAME
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Provided is a material for an organic EL device realizing an organic EL device capable of having a high current efficiency even at a low voltage. Provided is a derivative of heterocyclic compound having a nitrogen atom represented by the following general formula (A-1) or (A-2). In the formulae, R 1a to R 5a each represent a substituent, Ar 1a to Ar 3a each represent a single bond or a divalent connecting group, and HAr represents a group represented by a general formula (A-3) or (A-4). R 6a to R 10a each represent a substituent.
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Page/Page column 47
(2008/06/13)
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- NITROGEN-CONTAINING HETEROCYCLE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT USING THE SAME
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A novel derivative of heterocyclic compound having nitrogen atom with a structure made by bonding special groups to benzimidazole, a material for an organic electroluminescence (EL) device comprising the derivative of heterocyclic compound having nitrogen atom and an organic electroluminescence device comprising at least one organic compound layer containing a light emitting layer sandwiched between a pair of electrodes, wherein the device contains the derivative of heterocyclic compound having nitrogen atom. An organic EL device achieving elevation of luminance and of efficiency in light emission even under low driving voltage is obtainable by an employment of the derivative of heterocyclic compound having nitrogen atom for at least one layer composing organic compound layers of the EL device.
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Page/Page column 36
(2010/02/14)
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